
Updates:
The Uganda Ebola Virus outbreak that started in October
2000 has been determined to be over by the World Health organization (WHO) as
of 28 February 2001. The outbreak killed 224 people.
As of 16 April 2001, 86107 cases of Cholera have been reported
in the Kwa Zulu Natal Province of South Africa. There have been 181 deaths.
The new IATA and IMO Regulations have been plagued by almost
uncountable corrections. ADR/RID has not fared much better in Europe.
The original version of USG-12 in ICAO and IATA left out some
very important information about when the 24 hour emergency phone contact was
not required, such as consumer commodities and limited quantities. Added to
this problem is that some FAA enforcement personnel insist that shippers must
provide international access codes and area codes, etc. for U.S.-exported shipments.
USG-12 clearly states that the international access codes and area codes only
apply to emergency response numbers located outside the United States.
While a great number of "good-citizen" type shippers do provide this
information for emergency calls back to the U.S., it is not mandatory at this
time.
Do you need any more confusion? Nippon Cargo Airlines and Korean
Airlines have in-house requirements that both combination packagings and single
packaging drums of dangerous liquids must be banded to a pallet with another
pallet on the top of the drum. A few issues immediately come to mind: orientation
marks; "inner packages comply with prescribed regulations"; and the
wood pallet restrictions to some countries, which now appear to be turning into
a bigger problem with the EU enacting a similar ban.
Effective 1 October 2001, the European Communities will require
the treatment and marking of all coniferous wood packing materials originating
in the United States, Canada, Japan, and China in order to prevent infestation
by the pinewood nematode. (Source: HMAC).
Throw in rising fuel costs, mega mergers, the mad cow disease,
the change in subsidiary risk labels, airline passenger rage, airport congestion,
optional documentation procedures, and mid-year regulatory changes, then try
to tell us that Y2K was not a problem. Remember, the new millennium started
on 1 January 2001! Chaos reigns supreme! This is going to be some year.
Classifications
OK. Now that we vented, lets get back to classifications.
This month we are going to review Class 8, Corrosives.
There are two schools of thought about corrosives. One uses
"destruction" of the skin to describe a corrosive material. The other
uses "severe damage to skin" to define corrosives.
Everyone, we hope, agrees corrosion to steel and aluminum also poses a major
problem.
Since both of our schools ultimately arrive at skin destruction
as the criteria this would lead us to be into that rare position where we can
bring in the packing groups in an understandable way at the same time that we
are discussing corrosive properties.
Corrosives, packing group I (remember, we always use roman
numerals to indicate PG numbers), are defined as chemicals that cause total
destruction of the skin tissue within and observable time frame of 60 minutes
or less after an exposure of 3 minutes or less. Got that?
No?
All right then, let's ask for a volunteer. You. Yes, You!
Suppose we gave you a glass bottle of 75% nitric acid. That's
a PG I material.
And being a careless-type person, you dropped the bottle as
you were avoiding that forklift driver doing 50 mph through your warehouse.
The bottle breaks. The nitric acid splashes onto your clothes, soaking through
your slacks and onto your leg. The clothing will start smoldering almost immediately.
The nitric acid will almost instantly cause a burning sensation. "Sensation"?
A very mild description of what really happens - excrutiating pain!
Did you ever burn your hand or just your fingers with a match?
Multiply that by 10 and you might start to imagine how painful and permanent
the injury might be from nitric acid. The burn from a single match will hurt
for a few days and the skin will repair itself within a week or two. There should
be no permanent scar.
The nitric acid will "burn" through the layers of
the skin, layer by layer. It will accomplish the damage to the skin with an
exposure of 3 minutes or less. Further damage can only be prevented by continually
flushing the affected area for at least 20 minutes with constantly running water.
Hopefully, running water is nearby. After almost drowning you with water for
the 20 minutes we will all sit around and stare at you for another 40 minutes
- 20 minutes [the water] + 40 minutes [observing you] = 60 minutes. Remember,
a 3 (or less) minute exposure, then we observe our "volunteer" for
up to 60 minutes. And when we finally determine that, yes, you appear to have
permanent destruction of the skin, we can now confirm that our 75% nitric acid
was indeed a Packing Group I corrosive material.
Thanks for being a volunteer. As a reward you will be left
with a very ugly scar.
Of course, in the real world we do not ask for human volunteers.
That is why we have laboratory testing conducted by scientists and technicians.
The tests for skin corrosivity can be accomplished by using live rabbits or,
as an alternative, with National Authority approval, invitro testing. Human
experience can also be taken into consideration, but not ignorance.
The criteria for Packing Group II is based upon full destruction
of the skin after an exposure greater than 3 minutes, up to 1 hour. A 14 day
observation time frame is used after the affected area has been cleansed.
The criteria for Packing Group III is based upon full destruction
of the skin after an exposure of more than 1 hour up to a maximum of 4 hours.
A 14 day observation period is used after the affected area has been cleansed.
Even though a chemical does not destroy skin after an exposure
of 4 hours or less, it should be tested further to determine if it corrodes
steel or aluminum at a rate exceeding 6.25 mm (0.25 inch) per year. If it does,
the material is assigned to PG III.
Other factors:
pH - determines whether the corrosive is acidic (<7) or
basic (>7).
Organic - contains carbon (C) in its chemical structure.
Inorganic - does not contain carbon (C) in its chemical structure.
A transportation icon passes away.
I guess it was during the early or mid '60's that your editor was riding as
a passenger in an airline sales executive's car heading to Allentown, Pennsylvania
from Idlewild Airport in NYC. My "chauffer" had a CB radio in his
automobile since he frequently made lengthy trips by highway. We were in the
center lane of a three lane highway. We were right behind a big "18-wheeler"
and my driver got on his radio and started cursing out the very large tractor
trailer for hogging the "McLean Lane", more recently referred to as
the "sandwich" lane. That was my introduction to the McLean name and
to a trucking company known as the McLean Trucking Company. McLean's drivers
preferred the middle lane on highways since it almost always moved faster than
the traditionally slower right-hand lane. Other commercial drivers named the
lane after the trucking company, at least in the eastern part of the United
States. It has been indelibly imprinted in my mind all these years.
Malcom P. McLean, the founder of that trucking company, passed
away on Friday, May 25, 2001. He was 87 years old. The Associated Press carried
his obituary.
I've always associated the name with the trucking industry.
Much to my surprise, reading the Obit, I learned that he created containerization,
which now accounts for 90% of all cargo shipped by sea. He founded Sea-Land
Service and nurtured it into the world's largest container carrier. He was named
as the Man of the Century by the International Maritime Hall of Fame in 2000.
He owned 5 companies that were listed on the New York Stock Exchange and the
Nasdaq. He left an enormous legacy to the transportation industry.
Malcom, "we hardly got to know ye".
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